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詳細(xì)內(nèi)容:TPV 9101-45∟TPV 9101-45 PA46荷蘭DSM TS300 NC PA66日本旭化成14G25 ABS韓國(guó)LGHF-380U PMMA 上海贏創(chuàng)德固賽 8NDF21 PA66基礎(chǔ)創(chuàng)新塑料RL-4540 BK PMMA 日本三菱麗陽 TF8-000 EMMA美國(guó)杜邦A(yù)E PP沙特巴塞爾EP548S PA12 瑞士EMS TR-70 PBT基礎(chǔ)創(chuàng)新塑料VIC4311 BK1066L TPE德國(guó)膠寶TC9GPN PC日本出光 GZ2530 BK ETFE 日本旭硝子 CF-5020-X POM 德國(guó)泰科納 C27021 PA66韓國(guó)可隆KN333G15BLPPO 基礎(chǔ)創(chuàng)新塑料 GFN2 ABS寧波臺(tái)化AG15A3 PC基礎(chǔ)創(chuàng)新塑料 DFP36 PA6日本東洋紡織T-423TG PPO 基礎(chǔ)創(chuàng)新塑料 GTX830 PA6T 美國(guó)杜邦 HTN53G50LRHF HIPS美國(guó)陶氏1400 PA66美國(guó)杜邦101(粉) PBT日本寶理330EP-EF2001 PEI 基礎(chǔ)創(chuàng)新塑料 EFL4024EP PP廣州LG GP-3200PC/ABS 上?扑紕(chuàng)(拜耳) T-65 PA66美國(guó)杜邦HTN53G50LR GY758EMA法國(guó)阿科瑪AX8900 PP臺(tái)化B1101PPS日本出光L524J1X PP李長(zhǎng)榮PC 366-4 K(Q)膠日本電氣化學(xué)NSBC210PC基礎(chǔ)創(chuàng)新塑料 DS-1003FRHI PA66日本東麗CM6021M TPV 9101-45∟TPV 9101-45 TPV 9101-45∟TPV 9101-45 HIPS Impact resistant polystyrene (HIPS) is an impact resistant polystyrene product produced by adding polybutadiene rubber particles in polystyrene. introduce 475 is the HIPS machining TPV 9101-45∟TPV 9101-45 PC日本三菱工程 GSN-2030R2 POM/PTFE 基礎(chǔ)創(chuàng)新塑料 KL-4020-BK HDPE中石油獨(dú)山子HD4801EX PA12 瑞士EMS TR90 UV TPEE荷蘭DSM 63D PBT惠州南亞1403G3 GBK4 PC基礎(chǔ)創(chuàng)新塑料 DMX1214 PA66日本杜邦ST801HS BK010 EVA韓國(guó)韓華1316 SEBS美國(guó)科騰G1701 PC日本帝人 LD-1000RM LDPE伊朗國(guó)家石化LT0470/KJ PP中石油大慶HP500P EPDM 韓國(guó)SK S6090F EVA美國(guó)杜邦40L-03 PA11 法國(guó)阿科瑪 BESN P40 BLK T6L ABS廣州LGAF312B BK PC基礎(chǔ)創(chuàng)新塑料 DF1007 EVA美國(guó)杜邦560 PC基礎(chǔ)創(chuàng)新塑料(南沙) LS1-6164 PA6美國(guó)杜邦73G15HSL BK363 PC基礎(chǔ)創(chuàng)新塑料(南沙) EXL1433T PA11 法國(guó)阿科瑪 BESN NOIR P110TL GPPS佛山TOTAL1050 PBT基礎(chǔ)創(chuàng)新塑料(日本)457-70060731 PBT德國(guó)朗盛B7425 PA46荷蘭DSM TS271A1 PPO 基礎(chǔ)創(chuàng)新塑料 MX5669-BK1005 PA66德國(guó)巴斯夫A3EG10 NC PP韓國(guó)LG R3450 PBT/PET 德國(guó)朗盛 TP600-001POM 美國(guó)杜邦 100T PA66美國(guó)杜邦FE5382 ABS高膠粉天津大沽化工HR-GPEI 基礎(chǔ)創(chuàng)新塑料 2110 TPV 9101-45∟TPV 9101-45 TPV 9101-45∟TPV 9101-45 The impact resistance of PS can be processed by many traditional molding methods, such as injection molding, structural foam molding, sheet and film extrusion, hot forming and blow molding. HIPS resin absorbs water slowly, so there is no need for drying in general. Sometimes excessive moisture on the surface of the material will be absorbed, which affects the appearance quality of the final product. Under the temperature of 160 F dry 23h can remove excess moisture. The extrusion of thin films, sheets and profiles is the most useful processing method for HIPS. Anti impact polystyrene has a wide range of processing, so it becomes one of the most easily thermoforming resins. Generally, the melting temperature of the resin is 400 - 500 F, and the melt index range of the resin is 1.5 - 4 g/10min. Rotating, series and shuttle type pressure and vacuum thermoforming equipment are often used. HIPS has excellent thermal stability and shear stability. It can be used for a lot of recycled materials without reducing the performance of products, and the amount of recycled material in hot forming can be as high as 60%. TPV 9101-45∟TPV 9101-45 PC韓國(guó)LG K5030-739 PBT基礎(chǔ)創(chuàng)新塑料2735 BK1066 LLDPE中石化茂名7144-GD POM 美國(guó)泰科納 M450 PA66意大利LATIH2G/25-V0 PA12 日本宇部 3030JLX8 TPE美國(guó)吉力士OM 1255X-9 TPU拜耳優(yōu)得UT-68DU20 PA12 德國(guó)贏創(chuàng)德固賽 A4000 PP荷蘭利安德巴塞爾520PPS日本寶理6165D8 PP馬來大騰石化SM-546 PC臺(tái)化出光 A1600 POM 韓國(guó)工程塑料 NX-20 LDPE北歐化工LE6023 EVA泰國(guó)石化SV1055 AS(SAN)韓國(guó)LG80HF PC日本出光 LC1500M ETFE 日本旭硝子 C-55AP POM 日本旭化成 4060 PVC韓國(guó)LGPB900 PP基礎(chǔ)創(chuàng)新塑料G3240A PP韓國(guó)曉星J600F PA66美國(guó)杜邦10B40 POM 寶理 M270 PP甘肅蘭港石化H9018 PP寧波臺(tái)塑1080 PPO 基礎(chǔ)創(chuàng)新塑料 SE1X PA66美國(guó)首諾R513H LCP日本寶理S472 EVA新加坡聚烯烴KA-31 PP中石化茂名PPR-M55-S HDPE上海賽科HD5301AA POE西班牙陶氏8440 PA6日本尤尼吉可A1022GFL TPV 9101-45∟TPV 9101-45 TPV 9101-45∟TPV 9101-45 Injection molding is the most used processing method next to the extrusion. The injection molding of the resin is usually carried out on a reciprocating screw injection molding machine with a length to diameter ratio of 16:1 to 24:1 and a compression ratio of 2.5/1 - 3.0/1. The processing temperature is 350 - 500 degree F, but for the flame retardant HIPS, the processing temperature must be less than 470 F to prevent the additive from producing degradation reaction. The melt index of the resin processed by injection molding is generally 5 to 15 g/min. The forming method of structural foam plastics is a common process, using chemical and physical foaming agents. Although a variety of HIPS resin are compatible with each other, but before the operation to clean processing equipment, to ensure good product quality, the impact of acrylonitrile with a PS Th ene styrene copolymer (ABS), polyvinyl chloride (PVC), polypropylene (PP), polyethylene (PE), acrylic resin and most other plastics are not compatible, incompatible plastic mixture separation will produce delamination phenomenon in processing equipment, caused great decline of physical properties. application TPV 9101-45∟TPV 9101-45 PA12 瑞士EMS LV-3H-BK PBT日本寶理2016 POM 美國(guó)赫斯特 S 27063 PA12 法國(guó)阿托菲納 7033 PA9T 日本可樂麗 G1350H-F02-BK ABS/PMMA 韓國(guó)三星 BF-0950 TPUE385A ABS泰國(guó)朗盛532 PA66日本宇部2015SEG15 BKPOP美國(guó)陶氏1140G PBT日本三菱工程5308G45 PBT基礎(chǔ)創(chuàng)新塑料(南沙)DR48-7001 PP美國(guó)?松梨赑P8013L1 PEI 基礎(chǔ)創(chuàng)新塑料 2310R PA6美國(guó)舒爾曼6 NV 12FR PP中石油四川L5E89 TPV 荷蘭DSM 6145 ABS基礎(chǔ)創(chuàng)新塑料AFFRUV ABS日本電氣化學(xué)K-2110G BK PBT基礎(chǔ)創(chuàng)新塑料420 BK1066 POE美國(guó)陶氏7387 TPE德國(guó)膠寶AP1320004 MBS日本鐘淵M711 PA66日本東麗CM3001G33 B3 PA66日本旭化成1300G BK PC/ABS 日本帝人 TN-7500MC HDPE美國(guó)雪佛龍菲利普HHM5502BN PC日本帝人 ML-3110ZHP HDPE中石化茂名TR571M PC基礎(chǔ)創(chuàng)新塑料(南沙) EXL4019 PPS日本出光C-200SC PP基礎(chǔ)創(chuàng)新塑料MB-1006HS-S PC日本帝人 ML-2203 PBT美國(guó)杜邦6450XD EVA泰國(guó)石化WV1055 TPV 9101-45∟TPV 9101-45 TPV 9101-45∟TPV 9101-45 Impact resistance PS is easily machinability, good performance and low price, so it is used to manufacture products and industrial products of many uses. The main applications are packaging and disposable supplies, instruments, household appliances, toys and entertainment supplies, and construction industries. The largest use of HIPS is to be used as a packaging and disposable material, especially for food packaging and eating tableware. The main applications include the daily packaging container. A cup, a variety of covers, plates, bowls, etc. are used and distributed for the vending machine. Disposable products such as disc, bottle cap, safety razor, pen and so on are also a part of the use of HIPS. PVC carcinogen, which will undoubtedly affect the development of PVC to some extent. However, the residual VCM has been successfully reduced by vehicle and other ways, so that the content of VCM in PVC resin will be less than 10ppm, which will meet the requirement of hygienic grade resin and expand the application scope of PVC. Even the content of VCM in the resin is less than 5ppm, and the residual VCM is very few after processing. It is basically harmless to the human body and can be used as food and medicine packaging and children's toys. Main classification TPV 9101-45∟TPV 9101-45 PA66法國(guó)羅地亞1515MF8 BRT PPO 日本電氣化學(xué) ECF-60 PMMA 法國(guó)阿科瑪 HFI-15 PP沙特巴塞爾EP348U POM 美國(guó)泰科納 M90UV PEI 基礎(chǔ)創(chuàng)新塑料 EF1008 TPU德國(guó)科思創(chuàng)(拜耳)192 PPS菲利普R-4-02 PVC新疆圣雄能源SG-5 PEEK 英國(guó)威格斯 150FW30 PBT惠州南亞1210G3PC/ABS 德國(guó)科思創(chuàng)(拜耳) FR3005HF- PC日本三菱工程 LGS-2220M SIS南通臺(tái)橡DP-4211N PPS深圳東麗A310MX04 PA66美國(guó)杜邦70G33HS1L BK PA6T 日本三井化學(xué) C230K PP馬來大騰石化SM410R3 PC/ABS 廣州LG GN5008HFCOC美國(guó)泰科納6013F-04 POM 深圳杜邦 23P TPUZA906TS TPV 美國(guó)?松梨 111-50 PC日本帝人 ML-3120ZHP PP新加坡聚烯烴FL7015E2 TPE惠州李長(zhǎng)榮3411 PC日本住友化學(xué) LR8001V TPE美國(guó) APEXTB-1726UVE PC日本出光 URZ2502 PFA 美國(guó)杜邦 940HP PEI 基礎(chǔ)創(chuàng)新塑料 2300EPR ABS日本東麗950 PA46荷蘭DSM TE351 TPU美國(guó)路博潤(rùn)59300 POM 荷蘭杜邦 988PA TPV 9101-45∟TPV 9101-45 TPV 9101-45∟TPV 9101-45 According to the different application range, PVC can be divided into general PVC resin, high degree of polymerization PVC resin and crosslinked PVC resin. The general PVC resin by polymerization of vinyl chloride monomer is formed under the action of initiator; high degree of polymerization of PVC resin is resin in the polymerization of vinyl chloride monomer added to the system, the chain growth polymerization crosslinking agent; PVC resin is added to the resin crosslinking agent containing dienes and polyenes in vinyl chloride monomer polymerization polymerization system. According to the method to distinguish the vinyl chloride monomer, can be divided into electric stone, and imported ethylene (EDC, VCM) monomer method (on the habits of the ethylene monomer and import system called ethylene method). According to polymerization method, PVC can be divided into four main categories: suspension polyvinyl chloride, emulsion polymerization, polyvinyl chloride, bulk polymerization, polyvinyl chloride and solution polyvinyl chloride. Suspension polyvinyl chloride (PVC) is one of the most productive varieties, accounting for about 80% of the total output of PVC. Polyvinyl chloride suspension method is divided into six models according to absolute viscosity: XS-1, XS-2... XS-6; XJ-1, XJ-2... XJ-6. The meaning of each letter in the model: X- suspension; S- loose type; J- compact. method TPV 9101-45∟TPV 9101-45 HDPE臺(tái)塑7200 PA12 日本宇部 3014U PA6美國(guó)杜邦73GM30HSL2 BK LCP美國(guó)杜邦6330-BK010 PPS日本東麗A504X95 PA12 瑞士EMS TR 90 UV PA46荷蘭DSM TE250F6 PBT美國(guó)杜邦15315 LCP寶理E130i 205P PA66美國(guó)杜邦HTN53G50HSLR PA612瑞士EMS CF-6S TPEE長(zhǎng)春1163ML PP東莞韓華道達(dá)爾GH41 PA66美國(guó)首諾R543H HDPE沙特SABICM80064 PC基礎(chǔ)創(chuàng)新塑料(西班牙) 241-111 PC泰國(guó)三菱工程 H-3000R PBT杭州新光E202G30 EVA日本東洋紡織L-3388 PA12 瑞士EMS TR90 TL LDPE臺(tái)聚NA248 TPEE長(zhǎng)春1148XH PP惠州南亞3219M3 PC韓國(guó)三星 SC-1100UR PPS日本東麗E604 TPEE荷蘭DSM UM551-V POM 歐盟杜邦 DE20171 PA66美國(guó)杜邦1032L PC基礎(chǔ)創(chuàng)新塑料 EXL5689 PC基礎(chǔ)創(chuàng)新塑料(南沙) 953 PA12 日本宇部 3030U PA46荷蘭DSM UM551 NC PA6中石化巴陵BL2280 LLDPE加拿大諾瓦化學(xué)PF-0218B POM 德國(guó)泰科納 C13021 TPV 9101-45∟TPV 9101-45 TPV 9101-45∟TPV 9101-45 polyvinyl chloride PVC can be made by substitution reaction of ethylene, chlorine and catalyst. Because of its fire prevention heat effect of PVC is widely used in all walks of life every kind of products: wire skin, skin fiber, shoes, handbags, bags, accessories, signs and billboards, building decoration supplies, furniture, ornaments, rollers, pipes, toys (such as the famous Italy "Rody" jumping horse), curtain, door, auxiliary medical supplies, gloves, some food preservation paper, some fashion etc.. Polymerization method PVC was prepared by free radical addition polymerization. The polymerization methods were mainly divided into suspension polymerization, emulsion polymerization and bulk polymerization, mainly by suspension polymerization, which accounted for about 80% of the total output of PVC. The pure water, liquefied VCM monomer and dispersant were added to the reactor, then initiator and other auxiliaries were added. After heating to a certain temperature, the VCM monomer was polymerized by free radical to form PVC particles. Continuous stirring makes the particle size uniform and makes the generated particles suspended in the water. In addition, the PVC paste resin was produced by micro suspension, and the properties and paste properties of the products were all good. TPV 9101-45∟TPV 9101-45 PBT漳州長(zhǎng)春4830 BK PP中石油大慶Z30S SURLYN美國(guó)杜邦9150 POM 美國(guó)泰科納 MT8U01 PPE 日本旭化成 X583V PP臺(tái)化K9010 PFA 美國(guó)蘇威 F1930X PPE 日本旭化成 500V ABS基礎(chǔ)創(chuàng)新塑料GPM5500 PA11 基礎(chǔ)創(chuàng)新塑料(美國(guó)) HF-1006 TPEE長(zhǎng)春1148 PC韓國(guó)LG GN-2101F PBT漳州長(zhǎng)春4830 NCL PP福聚ST611 PPO 基礎(chǔ)創(chuàng)新塑料 PX1134 PC德國(guó)科思創(chuàng)(拜耳) 6485 LCP美國(guó)泰科納E471ID-2 PC韓國(guó)三星 IH-1040 G71770 PC/ABS 德國(guó)科思創(chuàng)(拜耳) T45 PA6荷蘭DSM K224-PG6 PA66荷蘭DSM J-1/30/15/TF PC上海三菱瓦斯 S-3000UR ABS奇美PA-758R PBT基礎(chǔ)創(chuàng)新塑料357XU-8269 PA/ABS德國(guó)巴斯夫N NM-10 PC/PTFE 基礎(chǔ)創(chuàng)新塑料 DFL-4536 BK POM 美國(guó)泰科納 AF30-01 PA66美國(guó)杜邦153HSL POM 荷蘭杜邦 500P PA66德國(guó)DOMO66ST4 PBT北化院301-G20FJ PC美國(guó)PTS PC -10GFR TPV 美國(guó)埃克森美孚 9101-75 PBT德國(guó)巴斯夫B 4300 K4 PA46日本DSM TW441 TPV 9101-45∟TPV 9101-45 TPV 9101-45∟TPV 9101-45 The monomer droplets are dispersed in the aqueous phase suspension polymerization method, using oil soluble initiator were dissolved in monomer, polymerization reaction in the droplet, the polymerization heat absorbed by the water in time, in order to ensure that these droplets in water were bead dispersed, need to join the suspension the stabilizer, such as gelatin and polyvinyl alcohol, methyl cellulose, hydroxyethyl cellulose, etc.. Most of the initiators are organic peroxide and azo compounds, such as peroxide two, two isopropyl carbonate, peroxide two, bicarbonate, peroxide two, two ethylhexyl ester, azo two isoheptane, azo two isobutadiene and so on. The polymerization is carried out in a polymerizer with a agitator. After polymerization, the monomer material flows into the recovery tank or stripper recycle monomer. Then into the mixing kettle, water washing then centrifuge dehydration, drying and resin finished products. The vinyl chloride monomer should be removed from the resin as much as possible. As the PVC for food packaging, the content of free monomer should be controlled below 1ppm. During polymerization, the temperature and pressure of the polymerization process must be controlled to ensure that the specified molecular weight and molecular weight distribution range are obtained and the detonation is prevented. The particle size and particle size distribution of the resin is controlled by the stirring speed and the selection and dosage of the suspension stabilizer. The quality of resin is characterized by particle size and particle size distribution, molecular weight and molecular weight distribution, apparent density, porosity, fisheye, thermostability, color, impurity content and free mobility of powder. Polymerization reaction
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